AIRGAS INC -- CARBON DIOXIDE- CO2, SOLID -- -
===================== Product Identification ===================== Product ID:CARBON DIOXIDE- CO2, SOLID MSDS Date:01/22/1999 FSC:NIIN:Submitter:D DG Status Code:A === Responsible Party === Company Name:AIRGAS INC Address:259 RADNOR-CHESTER RD SUITE 100 City:RADNOR State:PA ZIP:19087-5240 Country:US Info Phone Num:610-687-5253 Emergency Phone Num:800-424-9300(CHEMTREC) Resp. Party Other MSDS Num.:DOCUMENT # 1013 Chemtrec Ind/Phone:(800)424-9300 CAGE:TO065 === Contractor Identification === Company Name:AIRGAS INC Address:259 RADNOR-CHESTER RD SUITE 100 Box:City:RADNOR State:PA ZIP:19087-5240 Country:US Phone:610-687-5253 CAGE:TO065 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON DIOXIDE CAS:124-38-9 RTECS #:FF6400000 > Wt:99.8 Other REC Limits:NONE RECOMMENDED OSHA PEL:5000 PPM ACGIH TLV:5000PPM/30000STEL;96 Ingred Name:IMPURITIES Fraction by Wt: < 0.2% MAX Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD 50 ORAL RAT IS UNKNOWN. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:SOLID CARBON DIOXIDE (DRY ICE), IS A WHITE, OPAQUE SOLID WHICH RELEASES COLORLESS GAS. THE SOLID SUBLIMATES TO GAS QUICKLY AT STANDARD CONDITIONS, FORMING FOG IN AIR. THE MAIN HAZARDS ASSOCIATED WITH CARBON DIOXIDE ARE RELATED TO CARBON DIOXIDE GAS FORMATION AND THE COLD TEMPERATURE OF THE SOLID AND EVOLVED GAS. ACUTE:CONTACT WITH SOLID CARBON DIOXIDE OR COLD GAS CAN CAUSE FROSTBITE TO SKIN, EYES, AND OTHER EXPOSED TISSUE. CARBON DIOXIDE GAS IS AN ASPHYXIANT AND POWERFUL CEREBRAL VASODILATOR. INHALING HIGH CONCENTRATIONS OF CARBON DIOXIDE CAN LEAD TO COMA OR DEATH. AT LOW CONCENTRATIONS INHALA TION CAN CAUSE (SEE TOXICOLOGICAL) Explanation of Carcinogenicity:CARBON DIOXIDE IS NOT FOUND ON THE FOLLOWING LISTS: FEDERAL OSHA Z LIST, NTP, CAL/OSHA, IARC, AND THEREFORE IS NOT CONSIDERED TO BE, NOR SUSPECTED TO BE A CANCER-CAUSING AGENT BY THESE AGENCIES. Effects of Overexposure:INHALATION: LOW CONC.: NAUSEA, DIZZINESS, VISUAL DISTURBANCES, SHAKING, HEADACHE , MENTAL CONFUSION, SWEATING, INCREASED HEARTBEAT, ELEVATED BLOOD PRESS., INCREASED RESPIRATORY RATE. HIGH CONC: MAY CA USE EYE IRRITATION, EYE DAMAGE, COMA, DEATH. REVERSIBLE EFFECTS ON ACID-BASE BALANCE IN BLOOD, BLOOD PRESS., AND CIRCULATORY SYSTEM. COLD GAS CONTACT: CAN LEAD TO FROSTBITE, DERMATITIS, RED, CRACKED, IRRITATED SKIN, WITH EYES CAN CAUSE PAIN, REDNESS, BURNS, AND SEVERE EXPOSURE COLIC CAUSE BLINDNESS. MOIST AIR MAY LEAD TO CARBONIC ACID, AN EYE IRRITANT. Medical Cond Aggravated by Exposure:DISORDERS INVOLVING THE "TARGET ORGANS" MAY BE AGGRAVATED BY CARBON DIOXIDE OVEREXPOSURE. TARGET ORGANS: RESPIRATORY SYSTEM, CARDIOVASCULAR SYSTEM, EYES. ======================= First Aid Measures ======================= First Aid:RESCUERS SHOULD NOT ATTEMPT TO RETRIEVE VICTIMS OF EXPOSURE TO THIS PRODUCT WITHOUT ADEQUATE PERSONAL PROTECTIVE EQUIPMENT. AT A MINIMUM, SELF-CONTAINED BREATHING APPARATUS PERSONAL PROTECTIVE EQUIPME NT SHOULD BE WORN. REMOVE VICTIM TO FRESH AIR, AS QUICK AS POSSIBLE. TRAINED PERSONNEL SHOULD GIVE OXYGEN OR CPR AS NECESSARY. IN CASE OF FROSTBITE, PLACE FROSTBITTEN PART IN WARM WATER. DO NOT USE HO T WATER. IF WARM WATER IS NOT AVAILABLE, WRAP THE AFFECTED PART IN BLANKETS. ENCOURAGE VICTIM TO GENTLY EXERCISE THE AFFECTED PART WHILE BEING WARMED. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:NON-FLAMMABLE, INERT GAS. USE EXTINGUISHING MEDIA APPROPIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND FULL FACE-PIECE SELF-CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:CO2 DOES NOT BURN. CONTAINERS MAY BURST IN FIRE. DUSTS OF REACTIVE METALS (MAGNESIUM, ZIRCON, TITANIUM ALLOYS), MAY IGNITE AND EXPLODE IN PRESENCE OF CO2. MIXTURES OF CO2 WITH SODIUM AND POTASSIUM ALL OYS ARE IMPACT SENSITIVE AND EXPLODE VIOLENTLY. IN PRESENCE OF MOISTURE, CESIUM OXIDE IGNITES ON CONTACT WITH CO2. ================== Accidental Release Measures ================== Spill Release Procedures:UNCONTROLED RELEASES SHOULD BE RESPONDED TO BY TRAINED PERSONNEL USING PRE-PLANNED PROCEDURES. PROPER PROTECTIVE EQUIPMENT SHOULD BE USED. LOCATE AND SEAL SOURCE OF LEAKING GAS. ALLOW GAS, WHICH IS HE AVIER THAN AIR, TO DISSIPATE. MONITOR SURROUNDING AREA FOR CARBON DIOXIDE AND OXYGEN LEVELS. ATTEMPT TO CLOSE MAIN SOURCE VALVE PRIOR TO ENTERING AREA. IF NOT ABLE, ALLOW GAS TO RELEASE IN-PLACE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT HANDLE SOLID CO2 WITH BARE HANDS. USE HEAVY GLOVES OR ICE TONGS. HANDLE BLOCKS OF DRY ICE CAREFULLY, AS INJURIES CAN OCCUR IF ONE IS ACCIDENTALLY DROPPED ON THE FEET. NEVER STORE DRY ICE IN A S TANDARD REFRIGERATOR, COOLER, OR FREEZER DESIGNED FOR FOOD STORAGE. Other Precautions:CONTAINERS OF SOLID CARBON DIOXIDE SHOULD BE STORED UPRIGHT, FIRMLY SECURED TO PREVENT FALLING. CONTAINER SHOULD BE VENTED, NEVER STORE DRY ICE IN A GAS-TIGHT CONTAINER.TO PREVENT BUILD-UP OF GAS. CO NTAINERS SHOULD BE THERMALLY INSULATED AND KEPT AT LOWEST POSSIBLE TEMPERATURE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE SUPPLIED AIR RESPIRATOR IF CARBON DIOXIDE LEVELS ARE ABOVE RECOMMENDED LIMITS OR DURING EMERGENCY RESPONSE TO RELEASE OF THIS PRODUCT. IF APPROPRIATE, INSTALL AUTOMATIC MONITORING EQUIPMENT TO DET ECT THE LEVELS OF CARBON DIOXIDE AND OXYGEN. Ventilation:PROVIDE ADEQUATE NATURAL, LOCAL EXHAUST, AND/OR MECHANICAL(GENERAL) VENTILATION AS NEEDED TO PREVENT ACCUMULATION ABOVE THE TWA. Protective Gloves:WEAR LOW TEMPERATURE PROTECTIVE GLOVES. Eye Protection:SAFETY GLASSES, GOGGLES, OR FACE-SHIELDS. FACE-SHIELD MUST BE WORN FOR LIQUID. Other Protective Equipment:USE BODY PROTECTION APPROPRIATE FOR TASK. Work Hygienic Practices:NORMAL WORK HYGENIC PRACTICES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V1 Boiling Pt:=-78.5C, -109.3F Melt/Freeze Pt:=-56.6C, -69.9F Vapor Pres:844.7 PSIA Vapor Density:8.8 FT3/LB Spec Gravity:97.59 LB/FT3 @ -109.3F pH:3.7 (CARBONIC A Solubility in Water:0.90% @ 20C Appearance and Odor:COLORLESS TO OPAQUE, WHITE SOLID. ALL FORMS OF CO2 ARE ODORLESS AT LOW CONC. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES POWDERED ALUMINUM, BERYLIUM, CESIUM ALLOYS, CHROMIUM, MAGNESIUM-ALUMINUM ALLOYS, MANGANESE, THORIUM, TITANIUM, AND ZIRCONIUM. IN PRESENCE OF MOISTURE, CO2 WILL IGNITE WITH CESIUM OXIDE. METAL ACETYLIDES WILL ALSO IGNITE AND Stability Condition to Avoid:NORMALLY STABLE. DO NOT STORE THE SOLID FORM OF CARBON DIOXIDE IN GAS-TIGHT CONTAINERS, WHICH COULD ALSO CAUSE OVER-PRESSURIZATION AND RUPTURE OF THE CONTAINER. Hazardous Decomposition Products:CARBON DIOXIDE GAS IN AN ELECTRICAL DISCHARGE YIELDS CARBON MONOXIDE AND OXYGEN. IN THE PRESENCE OF MOISTURE, CARBON DIOXIDE WILL FORM CARBONIC ACID. Conditions to Avoid Polymerization:WILL NOT OCCUR. HOWEVER CARBON DIOXIDE ACTS TO CATALYZE THE POLYMERIZATION OF ACRYLLADEHYDE AND AZIRIDINE. =================== Toxicological Information =================== Toxicological Information:(FROM HEALTH HAZARDS) NAUSEA, DIZZINESS, VISUAL DISTURBANCES, SHAKING, HEADACHE, MENTAL CONFUSION, SWEATING, INCREASED HEATBEAT, ELEVATED BLOOD PRESSURE, AND RESPIRATORY RATE. HIGH CONCENTRATIONS IN A IR MAY CAUSE EYE IRRITATION, OR DAMAGE. CHRONIC: THERE ARE CURRENTLY NO KNOWN ADVERSE HEALTH EFFECTS ASSOCIATED WITH CHRONIC EXPOSURE TO SOLID CARBON DIOXIDE OR THE GAS WHICH IIS GENERATED BY SUBLIMAT ION. CARBON DIOXIDE IS NOT EXPECTED TO ADVERSELY AFFECT THE HUMAN REPRODUCTIVE SYSTEM IN RESPECT TO MUTAGENICITY, EMBRYOTOXICITY, TERATOGENICITY, AND REPRODUCTIVE TOXICITY. ===================== Ecological Information ===================== Ecological:ENVIRONMENTAL STABILITY: CARBON DIOXIDE FOOD CHAIN CONCENTRATION POTENTIAL: NONE. BIOLOGICAL DEMAND: NONE. EFFECTS OF PRODUCT ON PLANTS OR ANIMALS: ANY ADVERSE EFFECT ON ANIMALS WOULD BE RELATED TO CA RBON DIOXIDE OVEREXPOSURE AND OXYGEN-DEFICIENT ENVIRONMENTS. NO ADVERSE EFFECT IS ANTICIPATED TO OCCUR TO PLANT-LIFE, EXCEPT FOR FROST PRODUCED IN THE PRESENCE OF RAPIDLY EXPANDING GASES. EFFECT OF PR ODUCT ON AQUATIC LIFE: AQUATIC TOXICITY: 100-200 MG/L/NO TIME SPECIFIED/VARIOUS ORGANISMS/ FRESH WATER. WATERFOWL TOXICITY: INHALATION 5-8%, NO EFFECT. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE DISPOSAL MUST BE IN ACCORDANCE WITH APPROPRIATE FEDERAL, STATE, AND LOCAL REGULATIONS. RETURN CYLINDERS WITH ANY RESIDUAL PRODUCT TO ARGAS INC. DO NOT DISPOSE OF LOCALLY. =================== MSDS Transport Information =================== Transport Information:THIS MATERIAL IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U. S. DEPARTMENT OF TRANSPORTATION. PROPER SHIPPING NAME: CARBON DIOXIDE SOLID OR DRY ICE. HAZARD CLASS:9 (MISCELLANEOUS DANGEROUS GOODS) . UN 1845. PKG:I I I. DOT LABEL REQUIRED: NONE. NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (1996): 120. MARINE POLLUTANT: CARBON DIOXIDE IS NOT CLASSIFIED BY THE DOT AS A MARINE POLLUTANT ( A S DEFINED BY 49 CFR 172.101, APPENDIX B). TRANSPORTATION CANADA, TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: THIS MATERIAL IS CONSIDERED AS DANGEROUS GOODS. USE THE ABOVE INFORMATION FOR CANADIAN S HIPMENTS. ===================== Regulatory Information ===================== SARA Title III Information:CARBON DIOXIDE IS NOT SUBJECT TO THE REPORTING REQUIREMENTS OF SECTIONS 302, 304, AND 313 OF SARA, TITLE I I I. THERE ARE NO SPECIFIC THRESHOLD PLANNING QUANTITIES FOR CARBON DIOXIDE (SOLID, GASEOUS, OR LIQUID FORM). THE DEFAULT FEDERAL MSDS SUBMISSION AND INVENTORY REQUIREMENT FILING THRESHOLD OF 10,000 LBS (4,540 KG) THEREFORE APPLIES, PER 40 CFR 370.20. Federal Regulatory Information:U.S. CERCLA REPORTABLE QUANTITY (RQ): NOT APPLICABLE. U.S. TSCA INVENTORY STATUS: CARBON DIOXIDE IS ON THE TSCA INVENTORY. OTHER U.S. FEDERAL REGULATIONS: NOT APPLICABLE. CALIFORNIA SAFE DRINKING WATE R AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): CARBON DIOXIDE IS NOT ON THE CALIFORNIA PROPODITION 65 LISTS. State Regulatory Information:ALASKA- DESIGNATED TOXIC AND HAZARDOUS SUBSTANCES: CO2. CA.- PEL FOR CHEMICAL CONTAMINANTS: CO2. FL.-SUBSTANCE LIST: CO2. ILL.-TOXIC SUBSTANCE LIST: CO2. KA.- SECTION 302/313 LIST: NO. MASS.-SUBSTANCE LIST: CO2. MI.-CRITICAL MATERIAL REGISTER: NO. MINN.-LIST OF HAZARDOUS SUBSTANCES: CO2. MISSOURI-EMPLOYER INFO./ TOXIC SUBSTANCE LIST: CO2. N.J.-RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST: CO2. N. D.-LIS T OF HAZARDOUS CHEMICALS,(RQ): NO. PA-HAZARDOUS SUBSTANCE LIST: CO2. RI- HAZARDOUS SUBSTANCE LIST:CO 2. TX-HAZARDOUS SUBSTANCE LIST: NO. W. VA.-HAZARDOUS SUBSTANCE LIST: CO2. WIS.- TOXIC AND HAZARDOUS SUBSTANCES: CO2. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.